Product ID:212334-02334,HYJET IV-A PLUS
MSDS Date:06/01/1999
FSC:9150
NIIN:01-096-6497
Status Code:A
MSDS Number: CKFNH

EXXON COMPANY USA

HOUSTON, TX 77252-2810
US

Emergency Phone: 713-656-3424

Info Phone: 800-443-9966

Preparer: NOT PROVIDED.

Cage: 0TS34

EXXON MOBIL LUBRICANTS AND PETROLEUM SPECIALTIES CO.

FAIRFAX, VA 22037 US

Telephone: 703-846-4240

Cage: 0TS34

TRIBUTYL PHOSPHATE

CAS: 126-73-8

RTECS: TC7700000

OSHA PEL 5 MG/M3

ACGIH TLV: 2.2 MG/M3;0.2 PPM

AROMATIC PHOSPHATE

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

POLYMER ADDITIVES

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

ALIPHATIC EPOXIDES

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

LD50 LC50 Mixture:LD50 (ORAL, RAT) > 5,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF OVEREXPOSURE: PROLONGED OR
REPEATED SKIN CONTACT MAY CAUSE SKIN IRRITATION. REPEATED AND
PROLONGED OVEREXPOSURE TO OIL MISTS MAY RESULT IN DROPLET
DEPOSITION, OIL GRANULOMA FORMATION, INFLA MMATION AND INCREASED
INCIDENCE OF INFECTION. PROLONGED OR REPEATED CONTACT WITH THIS
PRODUCT TENDS TO REMOVE SKIN OILS, POSSIBLY LEADING TO IRRITATION
AND DERMATITIS. PRODUCT CONTACTING THE EYES WILL CAUSE EYE
IRRITATION. PRODUCT HAS A LOW ORDER OF ACUTE ORAL AND DERMAL
TOXICITY, BUT MINUTE AMOUNTS ASPIRATED INTO THE LUNGS DURING
INGESTION OR VOMITING MAY CAUSE MILD TO SEVERE PULMONARY INJURY AND
POSSIBLY DEATH.
Explanation of Carcinogenicity:IN ACCORDANCE WITH THE CURRENT OSHA
COMMUNICATION STANDARD CRITERIA, THIS PRODUCT DOES NOT REQUIRE A
CANCER HAZARD WARNING. THIS PRODUCT CONTAINS SYNTHETICALLY DERIVED
MATERIALS, AND AS SUCH IS NOT CH ARACTERIZED BY CURRENT IARC
CLASSIFICATION CRITERIA FOR OILS.
Effects of Overexposure:PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE
SKIN IRRITATION. PROLONGED OR REPEATED CONTACT WITH THIS PRODUCT
TENDS TO REMOVE SKIN OILS, POSSIBLY LEADING TO IRRITATION AND
DERMATITIS. PRODUCT CONTACTI NG THE EYES WILL CAUSE EYE IRRITATION.
PRODUCT HAS A LOW ORDER OF ACUTE ORAL AND DERMAL TOXICITY, BUT
MINUTE AMOUNTS ASPIRATED INTO THE LUNGS DURING INGESTION OR
VOMITING MAY CAUSE MILD TO SEVERE PULM ONARY INJURY AND POSSIBLY
DEATH.
Medical Cond Aggravated by Exposure:NONE RECOGNIZED.

First Aid:EYE CONTACT: IF SPLASHED INTO THE EYES, FLUSH WITH CLEAR
WATER FOR 15 MINUTES OR UNTIL IRRITATION SUBSIDES. IF IRRITATION
PERSISTS, CALL PHYSICIAN. SKIN: IN CASE OF CONTACT, WASH WITH SOAP
AND WATER. IF INJECTED INTO/UNDER SKIN, REGARDLESS OF THE
APPEARANCE OR ITS SIZE, CONTACT PHYSICIAN IMMEDIATELY. INHALATION:
VAPOR PRESSURE IS LOW AND INHALATION NORMALLY IS NOT A PROBLEM. IF
OVERCOME BY VAPOR F ROM HOT PRODUCT, IMMEDIATELY REMOVE FROM
EXPOSURE AND CALL A PHYSICIAN. IF BREATHING IS IRREGULAR/HAS
STOPPED, START RESUSCITATION, ADMINISTER OXYGEN IF AVAILABLE.
INGESTION: IF INGESTED, DO NOT INDUC E VOMITING; CALL PHYSICIAN
IMMEDIATELY.

Flash Point Method:COC
Flash Point:=177.8C, 352.F
MINIMUM
Autoignition Temp:=407.8C, 766.F
Lower Limits:NOT AVAILABL
Upper Limits:NOT AVAILABL
Extinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEMICAL, CARBON
DIOXIDE AND VAPORIZING LIQUID TYPE EXTINGUISHING AGENTS MAY ALL BE
SUITABLE FOR EXTINGUISHING FIRES INVOLVING THIS TYPE OF PRODUCT.
Fire Fighting Procedures:USE WATER TO KEEP FIRE EXPOSED CONTAINERS
COOL. IF A LEAK/SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE
THE VAPORS AND TO PROVIDE PROTECTION FOR PERSONS ATTEMPTING TO STOP
A LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY. USE
SUPPLIED-AIR BREATHING EQUIPMENT FOR ENCLOSED/CONFINED SPACES OR AS
OTHERWISE NEEDED.
Unusual Fire/Explosion Hazard:NOT PROVIDED.

Spill Release Procedures:RECOVER FREE PRODUCT. ADD SAND, EARTH OR OTHER
SUITABLE ABSORBENT TO SPILL AREA. MINIMIZE BREATHING VAPORS.
MINIMIZE SKIN CONTACT. OPEN ALL WINDOWS AND DOORS. KEEP PRODUCT OUT
OF SEWERS AND WATERCOURS ES BY DIKING OR IMPOUNDING. ADVISE
AUTHORITIES IF PRODUCT HAS ENTERED OR MAY ENTER SEWERS,
WATERCOURSES, OR EXTENSIVE LAND AREAS. ASSURE CONFORMITY WITH
APPLICABLE GOVERNMENTAL REGULATIONS.
Neutralizing Agent:NOT RELEVANT.

Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
DO NOT STORE NEAR HEAT, SPARKS, FLAME OR STRONG OXIDANTS. USE
PRODUCT WITH CAUTION AROUND HEAT, SPARKS, PILOT LIGHTS, STATIC
ELECTRICITY, AND OPEN FLAME.
Other Precautions:EMPTY CONTAINERS RETAIN PRODUCT RESIDUES (LIQUID
AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION;
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

Respiratory Protection:USE SUPPLIED-AIR RESPIRATORY PROTECTION IN
CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:USE LOCAL EXHAUST, IF NECESSARY. PROVIDE VENTILATION
SUFFICIENT TO PREVENT EXCEEDING RECOMMENDED EXPOSURE LIMIT OR
BUILDUP OF EXPLOSIVE CONCENTRATIONS OF VAPOR
Protective Gloves:USE CHEMICAL RESISTANT GLOVES TO AVOID PROLONGED OR
REPEATED SKIN CONTACT.
Eye Protection:USE SPLASH GOGGLES OR FACE SHIELD WHEN EYE CONTACT MAY
OCCUR.
Other Protective Equipment:USE CHEMICAL RESISTANT APRON OR OTHER
IMPERVIOUS CLOTHING, IF NEEDED, TO PREVENT SKIN CONTACT.
Work Hygienic Practices:TO PREVENT FIRE OR EXPLOSION RISK FROM STATIC
ACCUMULATION AND DISCHARGE, EFFECTVELY BOND AND/OR GROUND PRODUCT
TRANSFER SYSTEM IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION
ASSOCIATION PUBLICATIONS.
Supplemental Safety and Health
MINIMIZE BREATHING VAPOR, MIST OR FUMES. AVOID PROLONGED OR REPEATED
CONTACT WITH SKIN. REMOVE CONTAMINATED CLOTHING AND LAUNDER OR
DRY-CLEAN BEFORE REUSE.

HCC:V6
NRC/State Lic Num:NOT RELEVANT.
Boiling Pt:=287.8C, 550.F
B.P. Text:APPROXIMATELY
Melt/Freeze Pt:=-56.5C, -70.F
M.P/F.P Text:POUR POINT
Decomp Temp:Decomp Text:NOT PROVIDED.
Vapor Pres:0.5 @ 200F
Spec Gravity:0.995
pH:NOT RELEVANT.
Viscosity:10.33 CST @ 100F
Evaporation Rate & Reference:NO DATA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR PURPLE LIQUID, SWEET ODOR
Percent Volatiles by Volume:NEGLIGIBLE
Corrosion Rate:NOT PROVIDED.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDANTS SUCH AS LIQUID CHLORINE,
CONCENTRATED OXYGEN, SODIUM HYPOCHLORITE, CALCIUM HYPOCHLORITE,
NITRATES, PEROXIDES, ETC., AS THIS PRESENT A SERIOUS EXPLOSION
HAZARD.
Stability Condition to Avoid:WILL NOT REACT WITH WATER.
Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE, SULFUR
OXIDES, NITROGEN OXIDES, PHOSPHORUS OXIDES, ALDEHYDES AND OTHER
DECOMPOSITION PRODUCTS, IN THE CASE OF INCOMPLETE COMBUSTION.

Waste Disposal Methods:DRUMS SHOULD BE RETURNED TO A DRUM CONDITIONER.
ALL OTHER CONTAINERS SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY
SAFE MANNER AND IN ACCORDANCE WITH GOVERNMENTAL REGULATIONS.

Toxicological Information:THIS PRODUCT, AS MANUFACTURED BY EXXON, DOES
NOT CONTAIN POLYCHLORINATED BIPHENYLS (PCB'S). ACUTE DERMAL LD50
(RABBIT) GREATER THAN 3.16 G/KG. EXPOSURE LIMIT FOR TOTAL PRODUCT 5
MG/M3 FOR OIL MIST (AE ROSOL) FOR AN 8-HOUR WORKDAY. 3 MG/M3 FOR
TRIPHENYL PHOSPHATE FOR AN 8-HOUR WORKDAY. IN A LONG TERM FEEDING
STUDY IN MICE TRIBUTYL PHOSPHATE CAUSED AN INCREASE INCIDENCE OF
BENIGN LIVER TUMORS IN MALE CD-1 MICE (3500 PPM ONLY, NOEL = 1000
PPM) WHICH WAS ACCOMPANIED BY LIVER ENLARGEMENT. IN MALE AND FEMALE
CD RATS, A CHRONIC FEEDING STUDY RESULTED IN BENIGN AND MALIGNANT
TUMORS OF THE URINARY BLADD ER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:MAY BE TOXIC TO AQUATIC ORGANISMS.

Transport Information:U.S. DOT HAZARDOUS MATERIAL SHIPPING DESCRIPTION:
TRANSPORTED BY HIGHWAY, RAIL OR AIR (49 CFR 171-180) BULK
PACKAGINGS (CAPACITY GREATER THAN 119 U.S. GALLONS):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LI QUID, N.O.S. (TRIARYL
PHOSPHATES, ISOPROPYLATED), 9, UN 3082, III, MARINE POLLUTANT.
NON-BULK PACKAGINGS (CAPACITY LESS THAN OR EQUAL TO 119 U.S.
GALLONS) NOT REGULATED (49 CFR 171-180, IATA DGR 7.1.5 .2).
TRANSPORTED BY MARINE VESSEL: BULK AND NON-BULK PACKAGINGS (IMDG
7.2.1): ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(TRIARYL PHOSPHATES, ISOPROPYLATED), 9, UN 3082, III, MARINE
POLLUTANT .

SARA Title III Information:TOXIC CHEMICAL RELEASE REPORTING, EPA
REGULATION 40 CFR 372 (SARA SECTION 313): NO TOXIC CHEMICAL IS
PRESENT GREATER THAN 1% OR 0.1% (CARCINOGEN). TOXIC CHEMICAL
RELEASE REPORTING, EPA REGULATION 40 C FR 370 (SARA SECTION
311-312): EPA HAZARD CLASSIFICATION CODES: ACUTE, CHRONIC.
Federal Regulatory Information:TOXIC SUBSTANCE CONTROL ACT: THIS
PRODUCT CONTAINS THE FOLLOWING TSCA 12B REPORTABLE CHEMICAL
SUBSTANCE (S): TRIBUTYL PHOSPHATE CAS # 126-73-8.
State Regulatory Information:NOT PROVIDED.